From 3170fc4b5c915669cf209a521e551115a9bd0809 Mon Sep 17 00:00:00 2001 From: Prefetch Date: Wed, 20 Oct 2021 11:50:20 +0200 Subject: Expand knowledge base --- content/know/concept/boltzmann-relation/index.pdc | 96 +++++++++++++++++++++++ 1 file changed, 96 insertions(+) create mode 100644 content/know/concept/boltzmann-relation/index.pdc (limited to 'content/know/concept/boltzmann-relation') diff --git a/content/know/concept/boltzmann-relation/index.pdc b/content/know/concept/boltzmann-relation/index.pdc new file mode 100644 index 0000000..ddaa22f --- /dev/null +++ b/content/know/concept/boltzmann-relation/index.pdc @@ -0,0 +1,96 @@ +--- +title: "Boltzmann relation" +firstLetter: "B" +publishDate: 2021-10-18 +categories: +- Physics +- Plasma physics + +date: 2021-10-18T15:25:39+02:00 +draft: false +markup: pandoc +--- + +# Boltzmann relation + +In a plasma where the ions and electrons are both in thermal equilibrium, +and in the absence of short-lived induced electromagnetic fields, +their densities $n_i$ and $n_e$ can be predicted. + +By definition, a particle in an [electric field](/know/concept/electric-field/) $\vb{E}$ +experiences a [Lorentz force](/know/concept/lorentz-force/) $\vb{F}_e$. +This corresponds to a force density $\vb{f}_e$, +such that $\vb{F}_e = \vb{f}_e \dd{V}$. +For the electrons, we thus have: + +$$\begin{aligned} + \vb{f}_e + = q_e n_e \vb{E} + = - q_e n_e \nabla \phi +\end{aligned}$$ + +Meanwhile, if we treat the electrons as a gas +obeying the ideal gas law $p_e = k_B T_e n_e$, +then the pressure $p_e$ leads to another force density $\vb{f}_p$: + +$$\begin{aligned} + \vb{f}_p + = - \nabla p_e + = - k_B T_e \nabla n_e +\end{aligned}$$ + +At equilibrium, we demand that $\vb{f}_e = \vb{f}_p$, +and isolate this equation for $\nabla n_e$, yielding: + +$$\begin{aligned} + k_B T_e \nabla n_e + = q_e n_e \nabla \phi + \quad \implies \quad + \nabla n_e + = \frac{q_e \nabla \phi}{k_B T_e} n_e + = \nabla \bigg( \frac{q_e \phi}{k_B T_e} \bigg) n_e +\end{aligned}$$ + +This equation is straightforward to integrate, +leading to the following expression for $n_e$, +known as the **Boltzmann relation**, +due to its resemblance to the statistical Boltzmann distribution +(see [canonical ensemble](/know/concept/canonical-ensemble/)): + +$$\begin{aligned} + \boxed{ + n_e(\vb{r}) + = n_{e0} \exp\!\bigg( \!-\! \frac{q_e \phi(\vb{r})}{k_B T_e} \bigg) + } +\end{aligned}$$ + +Where the linearity factor $n_{e0}$ represents +the electron density for $\phi = 0$. +We can do the same for ions instead of electrons, +leading to the following ion density $n_i$: + +$$\begin{aligned} + \boxed{ + n_i(\vb{r}) + = n_{i0} \exp\!\bigg( \!-\! \frac{q_i \phi(\vb{r})}{k_B T_i} \bigg) + } +\end{aligned}$$ + +However, due to their larger mass, +ions are much slower to respond to fluctuations in the above equilibrium. +Consequently, after a perturbation, +the ions spend much more time in a transient non-equilibrium state +than the electrons, so this formula for $n_i$ is only valid +if the perturbation is sufficiently slow, +allowing the ions to keep up. +Usually, electrons do not suffer the same issue, +thanks to their small mass and fast response. + + +## References +1. P.M. Bellan, + *Fundamentals of plasma physics*, + 1st edition, Cambridge. +2. M. Salewski, A.H. Nielsen, + *Plasma physics: lecture notes*, + 2021, unpublished. -- cgit v1.2.3