---
title: "Young-Dupré relation"
firstLetter: "Y"
publishDate: 2021-03-07
categories:
- Physics
- Fluid mechanics
- Fluid statics
- Surface tension

date: 2021-03-07T15:05:50+01:00
draft: false
markup: pandoc
---

# Young-Dupré relation

In fluid mechanics, the **Young-Dupré relation** relates the contact
angle of a droplet at rest on a surface to the surface tensions of the interfaces.
Let $\alpha_{gl}$, $\alpha_{sl}$ and $\alpha_{sg}$ respectively be
the energy costs of the liquid-gas, solid-liquid and solid-gas interfaces:

$$\begin{aligned}
    \boxed{
        \alpha_{sg} - \alpha_{sl}
        = \alpha_{gl} \cos\theta
    }
\end{aligned}$$

The derivation is simple:
this is the only expression that maintains the droplet's boundaries
when you account for the surface tension force pulling along each interface.

A more general derivation is possible by using the
[calculus of variations](/know/concept/calculus-of-variations/).
In 2D, the upper surface of the droplet is denoted by $y(x)$.
Consider the following Lagrangian $\mathcal{L}$,
with the two first terms respectively being the energy costs
of the top and bottom surfaces:

$$\begin{aligned}
    \mathcal{L}
    = \alpha_{gl} \sqrt{1 + (y')^2} + (\alpha_{sl} - \alpha_{sg}) + \lambda y
\end{aligned}$$

And the last term comes from the constraint
that the volume $V$ of the droplet must be constant:

$$\begin{aligned}
    V = \int_0^L y \dd{x}
\end{aligned}$$

The total energy to be minimized is thus given by the following functional,
where the endpoints of the droplet are $x = 0$ and $x = L$:

$$\begin{aligned}
    E[y(x)]
    = \int_0^L \Big( \alpha_{gl} \sqrt{1 + (y')^2} + (\alpha_{sl} - \alpha_{sg}) + \lambda y \Big) \dd{x}
\end{aligned}$$

In this optimization problem, the endpoint $L$ is a free parameter,
i.e. the $L$-value of the optimum is unknown and must be found.
In such cases, the optimum $y(x)$ needs to satisfy the so-called *transversality condition*
at the variable endpoint, in this case $x = L$:

$$\begin{aligned}
    0
    &= \Big( \mathcal{L} - y' \pdv{\mathcal{L}}{y'} \Big)_{x = L}
    \\
    &= \bigg( \alpha_{gl} \sqrt{1 + (y')^2} + (\alpha_{sl} - \alpha_{sg}) + \lambda y - \frac{(y')^2}{\sqrt{1 + (y')^2}} \bigg)_{x = L}
    \\
    &= \bigg( \alpha_{gl} \frac{1}{\sqrt{1 + (y')^2}} + (\alpha_{sl} - \alpha_{sg}) + \lambda y \bigg)_{x = L}
\end{aligned}$$

Due to the droplet's shape, we have the boundary condition $y(L) = 0$,
so the last term vanishes.
We are thus left with the following equation:

$$\begin{aligned}
    \alpha_{gl} \frac{1}{\sqrt{1 + (y'(L))^2}}
    = \alpha_{sg} - \alpha_{sl}
\end{aligned}$$

At the edge of the droplet, imagine a small right-angled triangle
with one side $\dd{x}$ on the $x$-axis,
the hypotenuse on $y(x)$ having length $\dd{x} \sqrt{1 + (y')^2}$,
and the corner between them being the contact point with angle $\theta$.
Then, from the definition of the cosine:

$$\begin{aligned}
    \cos\theta
    = \frac{\dd{x}}{\dd{x} \sqrt{1 + (y'(L))^2}}
    = \frac{1}{\sqrt{1 + (y'(L))^2}}
\end{aligned}$$

When inserted into the above transversality condition,
this yields the Young-Dupré relation.



## References
1.  B. Lautrup,
    *Physics of continuous matter: exotic and everyday phenomena in the macroscopic world*, 2nd edition,
    CRC Press.