From cc391ce3b9867d88d124e147931d33be34e756fc Mon Sep 17 00:00:00 2001 From: Prefetch Date: Mon, 14 Sep 2026 18:11:38 +0200 Subject: Improve knowledge base --- source/know/concept/rabi-oscillation/index.md | 37 ++++++++++++++------------- 1 file changed, 19 insertions(+), 18 deletions(-) (limited to 'source/know/concept/rabi-oscillation/index.md') diff --git a/source/know/concept/rabi-oscillation/index.md b/source/know/concept/rabi-oscillation/index.md index 9497ad4..a2cea23 100644 --- a/source/know/concept/rabi-oscillation/index.md +++ b/source/know/concept/rabi-oscillation/index.md @@ -14,12 +14,12 @@ In quantum mechanics, we know from the [amplitude rate equations](/know/concept/amplitude-rate-equations/) that a time-dependent term $$\hat{H}_1$$ in the Hamiltonian affects the state as follows, -where $$c_n(t)$$ are the coefficients of the linear combination +where $$c_n(t)$$ are coefficients of a linear combination of unperturbed basis states $$\ket{n} e^{-i E_n t / \hbar}$$: $$\begin{aligned} i \hbar \dv{c_m}{t} - = \sum_{n} c_n(t) \matrixel{m}{\hat{H}_1}{n} e^{i \omega_{mn} t} + = \sum_{n} c_n(t) \matrixel{m}{\hat{H}_1(t)}{n} e^{i \omega_{mn} t} \end{aligned}$$ Where $$\omega_{mn} \equiv (E_m \!-\! E_n) / \hbar$$ @@ -36,7 +36,7 @@ $$\begin{aligned} \end{aligned}$$ Where $$\omega_0 \equiv \omega_{ba}$$ is positive. -We assume that $$\hat{H}_1$$ has odd spatial parity, +It is realistic to assume that $$\hat{H}_1$$ has odd spatial parity, in which case [Laporte's selection rule](/know/concept/selection-rules/) states that the diagonal matrix elements vanish, leaving: @@ -49,16 +49,16 @@ $$\begin{aligned} \end{aligned}$$ We now choose $$\hat{H}_1$$ to be as follows, -sinusoidally oscillating with a spatially odd $$V(\vec{r})$$: +sinusoidally oscillating with a spatially odd $$\hat{V}(\vec{r})$$: $$\begin{aligned} \hat{H}_1(t) - = V \cos(\omega t) - = \frac{V}{2} \Big( e^{i \omega t} + e^{-i \omega t} \Big) + = \hat{V} \cos(\omega t) + = \frac{\hat{V}}{2} \Big( e^{i \omega t} + e^{-i \omega t} \Big) \end{aligned}$$ We insert this into the equations for $$c_a$$ and $$c_b$$, -and define $$V_{ab} \equiv \matrixel{a}{V}{b}$$, leading us to: +and define $$V_{ab} \equiv \matrixel{a}{\hat{V}}{b}$$, leading us to: $$\begin{aligned} \dv{c_a}{t} @@ -124,7 +124,7 @@ which are found to be: $$\begin{aligned} \lambda_1 = i \frac{\omega - \omega_0 + \tilde{\Omega}}{2} - \qquad \quad + \qquad \qquad \lambda_2 = i \frac{\omega - \omega_0 - \tilde{\Omega}}{2} \end{aligned}$$ @@ -140,7 +140,7 @@ $$\begin{aligned} So that the general solution $$c_a(t)$$ is as follows, where $$A$$ and $$B$$ are arbitrary constants, -to be determined from initial conditions (and normalization): +determined by the initial conditions and normalization: $$\begin{aligned} \boxed{ @@ -154,7 +154,7 @@ from the coupled equation we started at, or, if we only care about the probability density $$|c_a|^2$$, we can use $$|c_b|^2 = 1 - |c_a|^2$$. For example, if $$A = 0$$ and $$B = 1$$, -we get the following probabilities +we get the following probabilities: $$\begin{aligned} |c_a(t)|^2 @@ -168,9 +168,8 @@ $$\begin{aligned} Note that the period was halved by squaring. This periodic "flopping" of the particle between $$\ket{a}$$ and $$\ket{b}$$ -is known as **Rabi oscillation**, **Rabi flopping** or the **Rabi cycle**. -This is a more accurate treatment -of the flopping found from first-order +is called **Rabi oscillation**, **Rabi flopping** or the **Rabi cycle**. +This is a more accurate treatment of the flopping found from first-order [time-dependent perturbation theory](/know/concept/time-dependent-perturbation-theory/). The name **generalized Rabi frequency** suggests @@ -183,11 +182,13 @@ $$\begin{aligned} \equiv \frac{V_{ba}}{\hbar} \end{aligned}$$ -Some authors use $$|V_{ba}|$$ instead, -but not doing that lets us use $$\Omega$$ as a nice abbreviation. -As an example, Rabi oscillation arises -in the [electric dipole approximation](/know/concept/electric-dipole-approximation/), -where $$\hat{H}_1$$ is: +Some authors write $$|V_{ba}|$$ instead, +but not doing so lets us use $$\Omega$$ as a nice abbreviation. +For example, Rabi oscillation arises for electrons +in an oscillating electric field (e.g. a light wave), +in which case $$\hat{H}_1$$ is as follows according to +the [electric dipole approximation](/know/concept/electric-dipole-approximation/), +with charge $$q < 0$$: $$\begin{aligned} \hat{H}_1(t) -- cgit v1.3