From 6e70f28ccbd5afc1506f71f013278a9d157ef03a Mon Sep 17 00:00:00 2001 From: Prefetch Date: Thu, 27 Oct 2022 20:40:09 +0200 Subject: Optimize last images, add proof template, improve CSS --- source/know/concept/selection-rules/index.md | 46 +++++++++++----------------- 1 file changed, 18 insertions(+), 28 deletions(-) (limited to 'source/know/concept/selection-rules') diff --git a/source/know/concept/selection-rules/index.md b/source/know/concept/selection-rules/index.md index 373486e..620e345 100644 --- a/source/know/concept/selection-rules/index.md +++ b/source/know/concept/selection-rules/index.md @@ -25,6 +25,7 @@ between $$\ell_i$$, $$\ell_f$$, $$m_i$$ and $$m_f$$, which, if not met, guarantee that the above matrix element is zero. + ## Parity rules Let $$\hat{O}$$ denote any operator which is odd under spatial inversion @@ -73,6 +74,7 @@ $$\begin{aligned} \end{aligned}$$ + ## Dipole rules Arguably the most common operator found in such matrix elements @@ -87,11 +89,8 @@ $$\begin{aligned} } \end{aligned}$$ -
- - - -
+{% include proof/end.html id="proof-dipole-m" %} + Meanwhile, for the total angular momentum $$\ell$$ we have the following: @@ -177,11 +176,8 @@ $$\begin{aligned} } \end{aligned}$$ -
- - - -
## Rotational rules @@ -502,11 +494,8 @@ $$\begin{aligned} } \end{aligned}$$ -
- - - -
+{% include proof/end.html id="proof-rotation-scalar" %} + Similarly, given a general (pseudo)vector operator $$\vu{V}$$, which, by nature, must satisfy the following commutation relations, @@ -631,6 +620,7 @@ $$\begin{gathered} \end{gathered}$$ + ## Superselection rule Selection rules are not always about atomic electron transitions, or angular momenta even. -- cgit v1.2.3