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Diffstat (limited to 'content/know/concept/kubo-formula/index.pdc')
-rw-r--r-- | content/know/concept/kubo-formula/index.pdc | 70 |
1 files changed, 11 insertions, 59 deletions
diff --git a/content/know/concept/kubo-formula/index.pdc b/content/know/concept/kubo-formula/index.pdc index f0208da..f5430da 100644 --- a/content/know/concept/kubo-formula/index.pdc +++ b/content/know/concept/kubo-formula/index.pdc @@ -35,7 +35,7 @@ $$\begin{aligned} = \matrixel{\psi_S(t)}{\hat{A}_S}{\psi_S(t)} &= \matrixel{\psi_I(t)}{\hat{A}_I(t)}{\psi_I(t)} \\ - &= \matrixel{\psi_I(t_0)}{\hat{K}_I^\dagger(t, t_0) \hat{A}_I(t) \hat{K}_I(t, t_0)}{\psi_I(t_0)} + &= \matrixel{\psi_I(t_0)\,}{\,\hat{K}_I^\dagger(t, t_0) \hat{A}_I(t) \hat{K}_I(t, t_0)\,}{\,\psi_I(t_0)} \end{aligned}$$ Where the time evolution operator $\hat{K}_I(t, t_0)$ is as follows, @@ -116,9 +116,12 @@ $$\begin{aligned} } \end{aligned}$$ -This result applies to bosonic operators, -whereas for fermionic operators -the commutator would be replaced by an anticommutator. +Note that observables are bosonic, +because in the [second quantization](/know/concept/second-quantization/) +they consist of products of even numbers +of particle creation/annihiliation operators. +Therefore, this correlation function +is a two-particle [Green's function](/know/concept/greens-functions/). A common situation is that $\hat{H}_1$ consists of a time-independent operator $\hat{B}$ @@ -133,67 +136,16 @@ $$\begin{aligned} = C^R_{A B}(t, t') f(t') \end{aligned}$$ -Conveniently, it can be shown that in this case -$C^R_{AB}$ only depends on the difference $t - t'$, -if we assume that the system was initially in thermodynamic equilibrium: +Since $C_{AB}^R$ is a Green's function, +we know that it only depends on the difference $t - t'$, +as long as the system was initially in thermodynamic equilibrium, +and $\hat{H}_{0,S}$ is time-independent: $$\begin{aligned} C^R_{A B}(t, t') = C^R_{A B}(t - t') \end{aligned}$$ -<div class="accordion"> -<input type="checkbox" id="proof-time-difference"/> -<label for="proof-time-difference">Proof</label> -<div class="hidden"> -<label for="proof-time-difference">Proof.</label> -This is trivial for $\Theta(t\!-\!t')$, -so the challenge is to prove that -$\expval*{\comm*{\hat{A}_I(t)}{B_I(t')}}$ -depends only on the time difference $t - t'$. - -Suppose that the system started in thermodynamic equilibrium -(see [canonical ensemble](/know/concept/canonical-ensemble/)), -so that its (unnormalized) [density operator](/know/concept/density-operator/) -$\hat{\rho}$ was as follows before $\hat{H}_{1,I}$ was applied: - -$$\begin{aligned} - \hat{\rho} = \exp\!(- \beta \hat{H}_{0,S}) -\end{aligned}$$ - -Let us assume that the perturbation $\hat{H}_{1,I}$ -does not affect the distribution of states, -but only their individual evolutions in time. -Note that, in general, this is not equilibrium. - -In that case, the expectation value of the product -of two time-independent observables $\hat{A}$ and $\hat{B}$ -can be calculated as follows, -where $Z_0 \equiv \Tr\!(\hat{\rho})$ is the partition function: - -$$\begin{aligned} - \expval*{\hat{A} \hat{B}} - = \frac{1}{Z_0} \Tr\!\big( \hat{\rho} \hat{A}_I \hat{H}_{1,I} \big) - = \frac{1}{Z_0} \Tr\!\Big( e^{-\beta \hat{H}_0} e^{i t \hat{H}_0 / \hbar} \hat{A}_S e^{-i t \hat{H}_0 / \hbar} - e^{i t' \hat{H}_0 / \hbar} \hat{B}_S e^{-i t' \hat{H}_0 / \hbar} \Big) -\end{aligned}$$ - -Where $\hat{H}_0 \equiv \hat{H}_{0,S}$ for brevity. -Using that the trace $\Tr$ is invariant -under cyclic permutations of its argument, -and that functions of $\hat{H}_{0,S}$ always commute, we find: - -$$\begin{aligned} - \expval*{\hat{A} \hat{B}} - = \frac{1}{Z_0} \Tr\!\Big( e^{-\beta \hat{H}_0} e^{i (t - t') \hat{H}_0 / \hbar} \hat{A}_S - e^{-i (t - t') \hat{H}_0 / \hbar} \hat{B}_S \Big) -\end{aligned}$$ - -As expected, this clearly only depends on the time difference $t - t'$, -because $\hat{H}_{0,S}$ is time-independent by assumption. -</div> -</div> - With this, the Kubo formula can be written as follows, where we have set $t_0 = - \infty$: |