diff options
Diffstat (limited to 'content/know/concept/time-dependent-perturbation-theory/index.pdc')
-rw-r--r-- | content/know/concept/time-dependent-perturbation-theory/index.pdc | 6 |
1 files changed, 3 insertions, 3 deletions
diff --git a/content/know/concept/time-dependent-perturbation-theory/index.pdc b/content/know/concept/time-dependent-perturbation-theory/index.pdc index 1fbd9ce..76ab684 100644 --- a/content/know/concept/time-dependent-perturbation-theory/index.pdc +++ b/content/know/concept/time-dependent-perturbation-theory/index.pdc @@ -59,13 +59,13 @@ We then take the inner product with an arbitrary stationary basis state $\ket{m} $$\begin{aligned} 0 - &= \sum_{n} \Big( \lambda c_n \matrixel{m}{\hat{H}_1}{n} - i \hbar \frac{d c_n}{dt} \braket{m}{n} \Big) \exp\!(- i E_n t / \hbar) + &= \sum_{n} \Big( \lambda c_n \matrixel{m}{\hat{H}_1}{n} - i \hbar \dv{c_n}{t} \braket{m}{n} \Big) \exp\!(- i E_n t / \hbar) \end{aligned}$$ Thanks to orthonormality, this removes the latter term from the summation: $$\begin{aligned} - i \hbar \frac{d c_m}{dt} \exp\!(- i E_m t / \hbar) + i \hbar \dv{c_m}{t} \exp\!(- i E_m t / \hbar) &= \lambda \sum_{n} c_n \matrixel{m}{\hat{H}_1}{n} \exp\!(- i E_n t / \hbar) \end{aligned}$$ @@ -74,7 +74,7 @@ $\omega_{mn} \equiv (E_m - E_n) / \hbar$ to get: $$\begin{aligned} \boxed{ - i \hbar \frac{d c_m}{dt} + i \hbar \dv{c_m}{t} = \lambda \sum_{n} c_n(t) \matrixel{m}{\hat{H}_1(t)}{n} \exp\!(i \omega_{mn} t) } \end{aligned}$$ |