In liquids, the Young-Laplace law governs surface tension: it describes the tension forces on a surface as a pressure difference between the two sides of the liquid.
Consider a small rectangle on the surface with sides and , orientated such that the sides are parallel to the (orthogonal) principal directions of the surface’ curvature.
Surface tension then pulls at the sides with a force of magnitude and , where is the energy cost per unit of area, which is the same as the force per unit of distance. However, due to the surface’ curvature, those forces are not quite in the same plane as the rectangle.
Along both principal directions, if we treat this portion of the surface as a small arc of a circle with a radius equal to the principal radius of curvature or , then the tension forces are at angles and calculated from the arc length:
Pay attention to the indices and : to get the angle of the force pulling at , we need to treat as an arc, and vice versa.
Since the forces are not quite in the plane, they have a small component acting perpendicular to the surface, with the following magnitudes and along the principal axes:
The initial factor of is there since the same force is pulling at opposide sides of the rectangle. We end up with multiplied by the surface area of the rectangle.
Adding together and and dividing out gives us the force-per-area (i.e. the pressure) added by surface tension, which is given by the Young-Laplace law:
The total excess pressure is called the Laplace pressure, and fully determines the effects of surface tension: a certain interface shape leads to a certain , and the liquid will flow (i.e. the surface will move) to try to reach an equilibrium.
- B. Lautrup, Physics of continuous matter: exotic and everyday phenomena in the macroscopic world, 2nd edition, CRC Press.
- T. Bohr, Surface tension and Laplace pressure, 2021, unpublished.