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diff --git a/content/know/concept/heisenberg-picture/index.pdc b/content/know/concept/heisenberg-picture/index.pdc new file mode 100644 index 0000000..2dd4118 --- /dev/null +++ b/content/know/concept/heisenberg-picture/index.pdc @@ -0,0 +1,117 @@ +--- +title: "Heisenberg picture" +firstLetter: "H" +publishDate: 2021-02-24 +categories: +- Quantum mechanics +- Physics + +date: 2021-02-24T16:46:26+01:00 +draft: false +markup: pandoc +--- + +# Heisenberg picture + +The **Heisenberg picture** is an alternative formulation of quantum +mechanics, and is equivalent to the traditionally-taught Schrödinger equation. + +In the Schrödinger picture, the operators (observables) are fixed +(as long as they do not depend on time), while the state +$\ket{\psi_S(t)}$ changes according to the Schrödinger equation, +which can be written using the generator of translations +$\hat{U}(t) = \exp{} (- i t \hat{H} / \hbar)$ like so: + +$$\begin{aligned} + \ket{\psi_S(t)} = \hat{U}(t) \ket{\psi_S(0)} +\end{aligned}$$ + +In contrast, the Heisenberg picture reverses the roles: +the states $\ket{\psi_H}$ are invariant, +and instead the operators vary with time. +An advantage of this is that the basis states remain the same. + +Given a Schrödinger-picture state $\ket{\psi_S(t)}$, and operator +$\hat{L}_S(t)$ which may or may not depend on time, they can be +converted to the Heisenberg picture by the following change of basis: + +$$\begin{aligned} + \boxed{ + \ket{\psi_H} = \ket{\psi_S(0)} + \qquad + \hat{L}_H(t) = \hat{U}^\dagger(t) \hat{L}_S(t) \hat{U}(t) + } +\end{aligned}$$ + +Since $\hat{U}(t)$ is unitary, the expectation value of a given operator is unchanged: + +$$\begin{aligned} + \expval*{\hat{L}_H} + &= \matrixel{\psi_H}{\hat{L}_H(t)}{\psi_H} + = \matrixel{\psi_S(0)}{\hat{U}^\dagger(t) \: \hat{L}_S(t) \: \hat{U}(t)}{\psi_S(0)} + \\ + &= \matrixel*{\hat{U}(t) \psi_S(0)}{\hat{L}_S(t)}{\hat{U}(t) \psi_S(0)} + = \matrixel{\psi_S(t)}{\hat{L}_S}{\psi_S(t)} + = \expval*{\hat{L}_S} +\end{aligned}$$ + +The Schrödinger and Heisenberg pictures therefore respectively +correspond to active and passive transformations by $\hat{U}(t)$ +in [Hilbert space](/know/concept/hilbert-space/). +The two formulations are thus entirely equivalent, +and can be derived from one another, +as will be shown shortly. + +In the Heisenberg picture, the states are constant, +so the time-dependent Schrödinger equation is not directly useful. +Instead, we will use it derive a new equation for $\hat{L}_H(t)$. +The key is that the generator $\hat{U}(t)$ is defined from the Schrödinger equation: + +$$\begin{aligned} + \dv{t} \hat{U}(t) = - \frac{i}{\hbar} \hat{H}_S(t) \hat{U}(t) +\end{aligned}$$ + +Where $\hat{H}_S(t)$ may depend on time. We differentiate the definition of +$\hat{L}_H(t)$ and insert the other side of the Schrödinger equation +when necessary: + +$$\begin{aligned} + \dv{\hat{L}_H}{t} + &= \dv{\hat{U}^\dagger}{t} \hat{L}_S \hat{U} + + \hat{U}^\dagger \hat{L}_S \dv{\hat{U}}{t} + + \hat{U}^\dagger \dv{\hat{L}_S}{t} \hat{U} + \\ + &= \frac{i}{\hbar} \hat{U}^\dagger \hat{H}_S (\hat{U} \hat{U}^\dagger) \hat{L}_S \hat{U} + - \frac{i}{\hbar} \hat{U}^\dagger \hat{L}_S (\hat{U} \hat{U}^\dagger) \hat{H}_S \hat{U} + + \Big( \dv{\hat{L}_S}{t} \Big)_H + \\ + &= \frac{i}{\hbar} \hat{H}_H \hat{L}_H + - \frac{i}{\hbar} \hat{L}_H \hat{H}_H + + \Big( \dv{\hat{L}_S}{t} \Big)_H + = \frac{i}{\hbar} [\hat{H}_H, \hat{L}_H] + \Big( \dv{\hat{L}_S}{t} \Big)_H +\end{aligned}$$ + +We thus get the equation of motion for operators in the Heisenberg picture: + +$$\begin{aligned} + \boxed{ + \dv{t} \hat{L}_H(t) = \frac{i}{\hbar} [\hat{H}_H(t), \hat{L}_H(t)] + \Big( \dv{t} \hat{L}_S(t) \Big)_H + } +\end{aligned}$$ + +This equation is closer to classical mechanics than the Schrödinger picture: +inserting the position $\hat{X}$ and momentum $\hat{P} = - i \hbar \: d/d\hat{X}$ +gives the following Newton-style equations: + +$$\begin{aligned} + \dv{\hat{X}}{t} + &= \frac{i}{\hbar} [\hat{H}, \hat{X}] + = \frac{\hat{P}}{m} + \\ + \dv{\hat{P}}{t} + &= \frac{i}{\hbar} [\hat{H}, \hat{P}] + = - \dv{V(\hat{X})}{\hat{X}} +\end{aligned}$$ + +For a proof, see [Ehrenfest's theorem](/know/concept/ehrenfests-theorem/), +which is closely related to the Heisenberg picture. |