diff options
Diffstat (limited to 'source/know/concept')
| -rw-r--r-- | source/know/concept/einstein-coefficients/index.md | 13 | ||||
| -rw-r--r-- | source/know/concept/fermi-gas/index.md | 33 | ||||
| -rw-r--r-- | source/know/concept/fermis-golden-rule/index.md | 222 | ||||
| -rw-r--r-- | source/know/concept/lehmann-representation/index.md | 28 | ||||
| -rw-r--r-- | source/know/concept/lindhard-function/index.md | 215 | ||||
| -rw-r--r-- | source/know/concept/parsevals-theorem/index.md | 6 | ||||
| -rw-r--r-- | source/know/concept/schwartz-distribution/index.md | 58 | ||||
| -rw-r--r-- | source/know/concept/time-dependent-perturbation-theory/index.md | 83 |
8 files changed, 438 insertions, 220 deletions
diff --git a/source/know/concept/einstein-coefficients/index.md b/source/know/concept/einstein-coefficients/index.md index ad75ce5..2367abc 100644 --- a/source/know/concept/einstein-coefficients/index.md +++ b/source/know/concept/einstein-coefficients/index.md @@ -157,10 +157,10 @@ $$\begin{aligned} = - q E_0 z \cos(\omega t) \end{aligned}$$ -This form of $$\hat{H}_1$$ is a well-known case for -[time-dependent perturbation theory](/know/concept/time-dependent-perturbation-theory/), -which tells us that the transition probability -from $$\ket{a}$$ to $$\ket{b}$$ is (to first order): +From the derivation of +[Fermi's golden rule](/know/concept/fermis-golden-rule/), +we then know that the probability $$P_{ab}$$ of a transition +from $$\ket{a}$$ to $$\ket{b}$$ is as follows (to first order): $$\begin{aligned} P_{ab} @@ -210,6 +210,7 @@ However, the result would not be constant in time $$t$$, so is not really useful. + ## Polarized light To solve this "problem", we generalize to (incoherent) polarized polychromatic light. @@ -238,8 +239,7 @@ $$\begin{aligned} \int_0^\infty \frac{\sin^2\!\big( (\omega_0 - \omega) t / 2 \big)}{(\omega_0 - \omega)^2} u(\omega) \dd{\omega} \end{aligned}$$ -From here, the derivation is similar to that of -[Fermi's golden rule](/know/concept/fermis-golden-rule/), +From here, the derivation is similar to that of Fermi's golden rule, despite the distinction that we are integrating over frequencies rather than states. At sufficiently large $$t$$, the integrand is sharply peaked at $$\omega = \omega_0$$ @@ -276,6 +276,7 @@ $$\begin{aligned} \end{aligned}$$ + ## Unpolarized light We can generalize the above result even further to unpolarized light. diff --git a/source/know/concept/fermi-gas/index.md b/source/know/concept/fermi-gas/index.md index 6d316cc..cd3d1a1 100644 --- a/source/know/concept/fermi-gas/index.md +++ b/source/know/concept/fermi-gas/index.md @@ -165,47 +165,38 @@ $$\begin{aligned} &= \frac{S}{6 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \varepsilon_F^{3/2} \end{aligned}$$ -The total population $$N = L^3 n$$ can therefore be expressed -as a function of $$\varepsilon_F$$: - -$$\begin{aligned} - N(\varepsilon_F) - &= \frac{S L^3}{6 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \varepsilon_F^{3/2} -\end{aligned}$$ - -And from this we obtain a formula for the -[density of states](/know/concept/density-of-states/) -$$g$$ of a 3D Fermi gas: +And from this we obtain the [density of states](/know/concept/density-of-states/) +$$g$$ per unit volume of a 3D Fermi gas: $$\begin{aligned} \boxed{ g(\varepsilon_F) - = \dv{N}{\varepsilon_F} - = \frac{S L^3}{4 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \varepsilon_F^{1/2} + = \dv{n}{\varepsilon_F} + = \frac{S}{4 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \varepsilon_F^{1/2} } \end{aligned}$$ Now, $$\varepsilon_F$$ is the highest energy of a single fermion, -but what about the total $$N$$-particle energy $$E$$? +but what about the total $$N$$-particle energy $$E$$ of the cube? This is easy to calculate using the density of states: $$\begin{aligned} - E + \frac{E}{L^3} &= \int_0^{\varepsilon_F} \varepsilon \: g(\varepsilon) \dd{\varepsilon} \\ - &= \frac{S L^3}{4 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} + &= \frac{S}{4 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \int_0^{\varepsilon_F} \varepsilon^{3/2} \dd{\varepsilon} \\ - &= \frac{3}{2} \frac{S L^3}{6 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \: \frac{2}{5} \varepsilon_F^{5/2} + &= \frac{3}{2} \frac{S}{6 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \: \frac{2}{5} \varepsilon_F^{5/2} \end{aligned}$$ -Here, we recognize $$N(\varepsilon_F)$$ from earlier, -leading to the following expression for the total $$E$$: +Here, we recognize $$n(\varepsilon_F)$$ from earlier, +leading to the following total $$E$$ per unit volume: $$\begin{aligned} \boxed{ - E - = \frac{3}{5} N \varepsilon_F + \frac{E}{L^3} + = \frac{3}{5} n \varepsilon_F } \end{aligned}$$ diff --git a/source/know/concept/fermis-golden-rule/index.md b/source/know/concept/fermis-golden-rule/index.md index ea58ee6..cce8894 100644 --- a/source/know/concept/fermis-golden-rule/index.md +++ b/source/know/concept/fermis-golden-rule/index.md @@ -10,74 +10,210 @@ categories: layout: "concept" --- -In quantum mechanics, **Fermi's golden rule** expresses -the transition rate between two states of a system, -when a sinusoidal perturbation is applied -at the resonance frequency $$\omega = E_g / \hbar$$ of the -energy gap $$E_g$$. The main conclusion is that the rate is independent of -time. +Consider a general quantum system that is being affected by a sinusoidal potential. +Specifically, the system's time-independent base Hamiltonian $$\hat{H}_0$$ +is perturbed by an $$\hat{H}_1(t)$$ given by: -From [time-dependent perturbation theory](/know/concept/time-dependent-perturbation-theory/), -we know that the transition probability -for a particle in state $$\Ket{a}$$ to go to $$\Ket{b}$$ -is as follows for a sinusoidal perturbation at frequency $$\omega$$: +$$\begin{aligned} + \hat{H}_1(\vb{r}, t) + \equiv \hat{V}(\vb{r}) \cos(\omega t) + = \frac{1}{2} \hat{V}(\vb{r}) \: (e^{i \omega t} + e^{-i \omega t}) +\end{aligned}$$ + +This potential is switched on at $$t = 0$$. +Let us study the system's response using +[time-dependent perturbation theory](/know/concept/time-dependent-perturbation-theory/), +by expressing the perturbed wavefunction $$\ket{\Psi(t)}$$ +as a superposition of known eigenstates $$\ket{n}$$ of $$\hat{H}_0$$ +with time-dependent coefficient $$c_n(t)$$: $$\begin{aligned} - P_{ab} - = \frac{|V_{ba}|^2}{\hbar^2} \frac{\sin^2\!\big((\omega_{ba} - \omega) t / 2\big)}{(\omega_{ba} - \omega)^2} + \ket{\Psi(t)} + = \sum_n c_n(t) \ket{n} e^{-i E_n t / h} \end{aligned}$$ -Where $$\omega_{ba} \equiv (E_b - E_a) / \hbar$$. -If we assume that $$\Ket{b}$$ irreversibly absorbs an unlimited number of particles, -then we can interpret $$P_{ab}$$ as the "amount" of the current particle -that has transitioned since the last period $$2 \pi n / (\omega_{ba} \!-\! \omega)$$. +In the absence of $$\hat{H}_1$$, +the coefficients would simply be constants $$c_n^{(0)}$$. +Perturbation theory then states that the first-order correction +$$c_n^{(1)}(t) \approx c_n(t) - c_n^{(0)}$$ is as follows, +with $$V_{mn} \equiv \matrixel{m}{\hat{V}}{n}$$: -For generality, let $$E_b$$ be the center -of a state continuum with width $$\Delta E$$. -In that case, $$P_{ab}$$ must be modified as follows, -where $$\rho(E_x)$$ is the destination's -[density of states](/know/concept/density-of-states/): +$$\begin{aligned} + c_m^{(1)}(t) + &= - \frac{i}{2 \hbar} \sum_{n} c_n^{(0)} \: V_{mn} + \int_0^t e^{i \tau (\omega_{mn} + \omega)} + e^{i \tau (\omega_{mn} - \omega)} \dd{\tau} + \\ + &= - \frac{1}{2 \hbar} \sum_{n} c_n^{(0)} \: V_{mn} + \bigg( \frac{e^{i t (\omega_{mn} + \omega)} - 1}{\omega_{mn} + \omega} + + \frac{e^{i t (\omega_{mn} - \omega)} - 1}{\omega_{mn} - \omega} \bigg) +\end{aligned}$$ + +For simplicity, we let the system start in a known state $$\ket{a}$$, +such that $$c_n^{(0)} = \delta_{na}$$, +and we focus on a single destination state $$m = b$$, +effectively turning this into a two-level system. +Let us assume that the driving frequency is close +to that transition's resonance $$\omega \approx \omega_{ba}$$, +such that the second term is dominant over the first, which can then be neglected. +We therefore get: $$\begin{aligned} - P_{ab} - &= \frac{|V_{ba}|^2}{\hbar^2} \int_{E_b - \Delta E / 2}^{E_b + \Delta E / 2} - \frac{\sin^2\!\big((\omega_{xa} - \omega) t / 2\big)}{(\omega_{xa} - \omega)^2} \:\rho(E_x) \dd{E_x} + c_b^{(1)}(t) + &= - \frac{V_{ba}}{2 \hbar} \frac{e^{i (\omega_{ba} - \omega) t} - 1}{\omega_{ba} - \omega} + \\ + &= - i \frac{V_{ba}}{2 i \hbar} \frac{e^{i (\omega_{ba} - \omega) t / 2} - e^{- i (\omega_{ba} - \omega) t / 2}}{\omega_{ba} - \omega} \: e^{i (\omega_{ba} - \omega) t / 2} + \\ + &= - i \frac{V_{ba}}{\hbar} \frac{\sin\!\big( (\omega_{ba} - \omega) t / 2 \big)}{\omega_{ba} - \omega} \: e^{i t (\omega_{ba} - \omega) / 2} +\end{aligned}$$ + +Taking the norm squared yields the **transition probability**: +the probability that a particle starting in state $$\ket{a}$$ +will be found in $$\ket{b}$$ at time $$t > 0$$: + +$$\begin{aligned} + \boxed{ + P_{a \to b}(t) + = |c_b^{(1)}(t)|^2 + = \frac{|V_{ba}|^2}{\hbar^2} \frac{\sin^2\!\big( (\omega_{ba} - \omega) t / 2 \big)}{(\omega_{ba} - \omega)^2} + } \end{aligned}$$ -If $$E_b$$ is not in a continuum, then $$\rho(E_x) = \delta(E_x - E_b)$$. -The integrand is a sharp sinc-function around $$E_x$$. -For large $$t$$, it is so sharp that we can take out $$\rho(E_x)$$. -In that case, we also simplify the integration limits. -Then we substitute $$x \equiv (\omega_{xa}\!-\!\omega) / 2$$ to get: +This would be the same if $$\hat{H}_1 \equiv \hat{V} \sin(\omega t)$$. +However, many authors define $$\hat{H}_1 \equiv \hat{V} e^{- i \omega t}$$, +and then $$P_{a \to b}$$ is larger by a factor of $$4$$, +which can cause confusion when comparing literature. + +In any case, the probability oscillates as a function of $$t$$ +with period $$T = 2 \pi / (\omega_{ba} - \omega)$$, +so after one full period the particle is back in $$\ket{a}$$, +and after $$T/2$$ the particle is fully in $$\ket{b}$$. +See [Rabi oscillation](/know/concept/rabi-oscillation/) +for a more accurate treatment of this "flopping" behaviour. + +However, when regarded as a function of $$\omega$$, the probability +takes the form of a sinc-function centred around $$(\omega_{ba} - \omega)$$, +so it is maximized for transitions with energy +$$\hbar \omega = E_b - E_a$$. +Also notice that the sinc-function becomes narrower over time: +this has no effect if $$\omega = \omega_{ba}$$, +however, if we are slightly off-resonance, +then this means that $$P_{a \to b}$$ decreases over time. + +In fact, for $$t \to \infty$$, the sinc-function +becomes so sharp that it can be related to +the [Dirac delta function](/know/concept/dirac-delta-function/) $$\delta$$. +Consider this general identity (yes, the notation is sloppy, but it is clear): $$\begin{aligned} - P_{ab} - &\approx \frac{2}{\hbar} |V_{ba}|^2 \rho(E_b) \int_{-\infty}^\infty \frac{\sin^2(x t)}{x^2} \:dx + \lim_{t \to \infty} \frac{\sin^2(x t / 2)}{x^2} + = \frac{\pi}{2} \: \delta(x) \: t \end{aligned}$$ -This definite integral turns out to be $$\pi |t|$$, -so we find, because clearly $$t > 0$$: + +{% include proof/start.html id="proof-relation" -%} +First, observe that we can rewrite the fraction using an integral: $$\begin{aligned} - P_{ab} - &= \frac{2 \pi}{\hbar} |V_{ba}|^2 \rho(E_b) \: t + \frac{\sin(x t / 2)}{x} + = \frac{e^{i x t / 2} - e^{-i x t / 2}}{2 i x} + = \frac{i}{2 i} \int_{-t/2}^{t/2} e^{i x \tau} \dd{\tau} \end{aligned}$$ -The transition rate $$R_{ab}$$, +By taking the limit $$t \to \infty$$, +it can be turned into a nascent Dirac delta function: + +$$\begin{aligned} + \lim_{t \to \infty} \frac{\sin(x t / 2)}{x} + = \lim_{t \to \infty} \frac{\pi}{2 \pi} \int_{-\infty}^{\infty} e^{i x \tau} \dd{\tau} + = \lim_{t \to \infty} \pi \delta(x) +\end{aligned}$$ + +On the topic of the delta function, we also show that its square is given by: + +$$\begin{aligned} + \delta^2(x) + = \delta(x) \lim_{t \to \infty} \frac{1}{2 \pi} \int_{-t/2}^{t/2} e^{i x \tau} \dd{\tau} + = \delta(x) \lim_{t \to \infty} \frac{t}{2 \pi} +\end{aligned}$$ + +Where we have set $$x = 0$$ according to the first delta function. +This gives the target: + +$$\begin{aligned} + \lim_{t \to \infty} \frac{\sin^2(x t / 2)}{x^2} + = \pi^2 \delta^2(x) + = \frac{\pi}{2} \: \delta(x) \: t +\end{aligned}$$ +{% include proof/end.html id="proof-relation" %} + + +Inserting this into $$P_{a \to b}$$ +and using the general property that $$\delta(x) / c = \delta(c x)$$: + +$$\begin{aligned} + P_{a \to b} + &= \frac{\pi t}{2 \hbar^2} |V_{ba}|^2 \: \delta(\omega_{ba} - \omega) + \\ + &= \frac{\pi t}{2 \hbar} |V_{ba}|^2 \: \delta(E_b - E_a - \hbar \omega) +\end{aligned}$$ + +By taking the $$t$$-derivative, we obtain the **transition rate** $$R_{a \to b}$$, i.e. the number of particles per unit time, -then takes this form: +which is given by **Fermi's golden rule**: + +$$\begin{aligned} + \pdv{P_{a \to b}}{t} = + \boxed{ + R_{a \to b} + = \frac{\pi}{2 \hbar} |V_{ba}|^2 \: \delta(E_b - E_a - \hbar \omega) + } +\end{aligned}$$ + +Once again, beware that many authors define +$$\hat{H}_1 \equiv \hat{V} e^{- i \omega t}$$, +in which case the result is larger by a factor of $$4$$, +which can cause confusion when comparing literature. +For that alternative derivation, see the one-photon section of +[multi-photon absorption](/know/concept/multi-photon-absorption/). + +What is most noteworthy about this result is +that the $$t$$-dependence has disappeared, +and that the rate is proportional to $$|V_{ba}|^2$$, +i.e. the overlap between $$\ket{a}$$ and $$\ket{b}$$ with respect to $$\hat{V}$$. +In practice, this result is usually used inside an integral over $$\omega$$, +hence that "naked" Dirac delta function. + +For generality, let us take $$E_b$$ to be the center +of a state continuum with width $$2 W$$. +In that case, $$P_{a \to b}$$ must be modified as follows, +where $$\rho(E_x)$$ is the destination's +[density of states](/know/concept/density-of-states/): + +$$\begin{aligned} + P_{a \to b} + &= \frac{|V_{ba}|^2}{\hbar^2} \int_{E_b - W}^{E_b + W} + \frac{\sin^2\!\big((\omega_{xa} - \omega) t / 2\big)}{(\omega_{xa} - \omega)^2} \:\rho(E_x) \dd{E_x} + \\ + &= \frac{\pi t}{2 \hbar} |V_{ba}|^2 + \int_{E_b - W}^{E_b + W} \delta(E_x - E_a - \hbar \omega) \: \rho(E_x) \dd{E_x} + \\ + &= \frac{\pi t}{2 \hbar} |V_{ba}|^2 \rho(E_a + \hbar \omega) +\end{aligned}$$ + +Where we used the aforementioned relation for $$t \to \infty$$ again. +The transition rate is therefore: $$\begin{aligned} + \pdv{P_{a \to b}}{t} = \boxed{ - R_{ab} - = \pdv{P_{ab}}{t} - = \frac{2 \pi}{\hbar} |V_{ba}|^2 \rho(E_b) + R_{a \to b} + = \frac{\pi}{2 \hbar} |V_{ba}|^2 \, \rho(E_b) } \end{aligned}$$ -Note that the $$t$$-dependence has disappeared, -and all that remains is a constant factor involving $$E_b = E_a \!+\! \hbar \omega$$, -where $$\omega$$ is the resonance frequency. +This is an alternative version of Fermi's golden rule. +Unsurprisingly, if $$E_b$$ is not in a continuum, +then we simply have $$\rho(E_x) = \delta(E_b - E_x)$$ and recover the previous version. diff --git a/source/know/concept/lehmann-representation/index.md b/source/know/concept/lehmann-representation/index.md index 0dec718..d96eb66 100644 --- a/source/know/concept/lehmann-representation/index.md +++ b/source/know/concept/lehmann-representation/index.md @@ -78,7 +78,8 @@ $$\begin{aligned} } \end{aligned}$$ -We now go through the same process for the lesser Green's function $$G_{\nu \nu'}^<(t, t')$$: +We now go through the same process +for the lesser Green's function $$G_{\nu \nu'}^<(t, t')$$: $$\begin{aligned} G_{\nu \nu'}^<(t - t') @@ -137,20 +138,22 @@ $$\begin{aligned} \\ &= - \frac{i}{\hbar Z} \Theta(t \!-\! t') \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} - \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) e^{i (E_n - E_{n'}) (t - t') / \hbar} + \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) e^{i (E_n - E_{n'}) (t - t') / \hbar} \end{aligned}$$ We take the Fourier transform, but to ensure convergence, -we must introduce an infinitesimal positive $$\eta \to 0^+$$ to the exponent +we introduce an infinitesimal positive $$\eta \to 0^+$$ to the exponent (and eventually take the limit): $$\begin{aligned} G_{\nu \nu'}^R(\omega) - &= - \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) \int_{-\infty}^\infty \Theta(t) e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega + i \eta) t} \dd{t} + &= - \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) + \int_{-\infty}^\infty \Theta(t) e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega + i \eta) t} \dd{t} \\ - &= - \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) \int_0^\infty e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega + i \eta) t} \dd{t} + &= - \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) + \int_0^\infty e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega + i \eta) t} \dd{t} \\ - &= - \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) + &= - \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) \bigg[ \frac{\hbar e^{i (\hbar \omega + E_n - E_{n'}) t / \hbar} e^{- \eta t}}{i (\hbar \omega + E_n - E_{n'}) - \hbar \eta} \bigg]_0^\infty \end{aligned}$$ @@ -166,7 +169,8 @@ $$\begin{aligned} } \end{aligned}$$ -Finally, we go through the same steps for the advanced Green's function $$G_{\nu \nu'}^A(t, t')$$: +Finally, we go through the same steps +for the advanced Green's function $$G_{\nu \nu'}^A(t, t')$$: $$\begin{aligned} G_{\nu \nu'}^A(t \!-\! t') @@ -174,7 +178,7 @@ $$\begin{aligned} \\ &= \frac{i}{\hbar Z} \Theta(t' \!-\! t) \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} - \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) e^{i (E_n - E_{n'}) (t - t') / \hbar} + \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) e^{i (E_n - E_{n'}) (t - t') / \hbar} \end{aligned}$$ For the Fourier transform, we must again introduce $$\eta \to 0^+$$ @@ -182,11 +186,13 @@ For the Fourier transform, we must again introduce $$\eta \to 0^+$$ $$\begin{aligned} G_{\nu \nu'}^A(\omega) - &= \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) \int_{-\infty}^\infty \Theta(-t) e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega - i \eta) t} \dd{t} + &= \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) + \int_{-\infty}^\infty \Theta(-t) e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega - i \eta) t} \dd{t} \\ - &= \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) \int_{-\infty}^0 e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega - i \eta) t} \dd{t} + &= \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) + \int_{-\infty}^0 e^{i (E_n - E_{n'}) t / \hbar} e^{i (\omega - i \eta) t} \dd{t} \\ - &= \frac{i}{\hbar Z} \sum_{n n'} \Big( ... \Big) + &= \frac{i}{\hbar Z} \sum_{n n'} \matrixel{n}{\hat{c}_\nu}{n'} \matrixel{n'}{\hat{c}_{\nu'}^\dagger}{n} \Big( e^{-\beta E_n} \mp e^{- \beta E_{n'}} \Big) \bigg[ \frac{\hbar e^{i (\hbar \omega + E_n - E_{n'}) t / \hbar} e^{\eta t}}{i (\hbar \omega + E_n - E_{n'}) + \hbar \eta} \bigg]_{-\infty}^0 \end{aligned}$$ diff --git a/source/know/concept/lindhard-function/index.md b/source/know/concept/lindhard-function/index.md index 1e3c675..67af408 100644 --- a/source/know/concept/lindhard-function/index.md +++ b/source/know/concept/lindhard-function/index.md @@ -376,30 +376,46 @@ $$\begin{aligned} - \int_{-\infty}^{\infty} \frac{n_F(\xi_{- \vb{k}'})}{\xi_{- \vb{k}' - \vb{q}} - \xi_{- \vb{k}'} + \hbar (\omega + i \eta)} \dd{\vb{k}'} \bigg) \\ - &= \frac{1}{4 \pi^3} \int_{-\infty}^{\infty} n_F(\xi_{\vb{k}}) \bigg( + &= \frac{1}{4 \pi^3} \int_{-\infty}^{\infty} \bigg( \frac{1}{\xi_{\vb{k}} - \xi_{\vb{k} + \vb{q}} + \hbar (\omega + i \eta)} + \frac{1}{\xi_{\vb{k}} - \xi_{\vb{k} + \vb{q}} - \hbar (\omega + i \eta)} - \bigg) \dd{\vb{k}} + \bigg) n_F(\xi_{\vb{k}}) \dd{\vb{k}} +\end{aligned}$$ + +Considering the system's symmetry, it is natural +to switch to [spherical coordinates](/know/concept/spherical-coordinates/) +$$(|\vb{k}|, \theta, \varphi)$$: + +$$\begin{aligned} + \chi_0 + &= \frac{1}{4 \pi^3} \int_0^\infty \!\! \int_0^\pi \! \int_{-\pi}^\pi \! \bigg( + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} + \hbar (\omega \!+\! i \eta)} + + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} - \hbar (\omega \!+\! i \eta)} + \bigg) n_F(\xi_{\vb{k}}) \, |\vb{k}|^2 \sin{\theta} \dd{\varphi} \dd{\theta} \dd{|\vb{k}|} + \\ + &= \frac{2 \pi}{4 \pi^3} \int_0^\infty \!\! \int_0^\pi \bigg( + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} + \hbar (\omega \!+\! i \eta)} + + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} - \hbar (\omega \!+\! i \eta)} + \bigg) n_F(\xi_{\vb{k}}) \, |\vb{k}|^2 \sin{\theta} \dd{\theta} \dd{|\vb{k}|} \end{aligned}$$ At absolute zero $$T = 0$$, the Fermi gas has a well-known ground state, in which the occupied single-particle plane wave states form a sphere in $$\vb{k}$$-space with radius $$k_F$$. -In that case, $$n_F(\xi_\vb{k})$$ reduces to -a Heaviside step function $$\Theta(k_F - |\vb{k}|)$$. -We switch to [spherical coordinates](/know/concept/spherical-coordinates/) -$$(|\vb{k}|, \theta, \varphi)$$ and adjust $$|\vb{k}|$$'s -integration limit based on the step function's demand that $$|\vb{k}| < k_F$$: +This is a good approximation for nonzero $$T$$ too, because in practice, +the electrons' Fermi level $$\xi_F \equiv \hbar^2 k_F^2 / (2 m)$$ +is huge compared to thermal excitations. +Formally, $$n_F(\xi_\vb{k}) \approx \Theta(k_F - |\vb{k}|)$$, +so we adjust the integration limit: $$\begin{aligned} - \chi_0(\vb{q}, \omega) - &= \frac{2 \pi}{4 \pi^3} \int_0^{k_F} \! \int_0^\pi - \bigg( \frac{1}{\xi_{\vb{k}} - \xi_{\vb{k} + \vb{q}} + \hbar (\omega \!+\! i \eta)} - + \frac{1}{\xi_{\vb{k}} - \xi_{\vb{k} + \vb{q}} - \hbar (\omega \!+\! i \eta)} \bigg) |\vb{k}|^2 \sin{\theta} \dd{\theta} \dd{|\vb{k}|} + \chi_0 + &\approx \frac{1}{2 \pi^2} \int_0^{k_F} \! \int_0^\pi \bigg( + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} + \hbar (\omega \!+\! i \eta)} + + \frac{1}{\xi_{\vb{k}} \!-\! \xi_{\vb{k} + \vb{q}} - \hbar (\omega \!+\! i \eta)} + \bigg) |\vb{k}|^2 \sin{\theta} \dd{\theta} \dd{|\vb{k}|} \end{aligned}$$ -Where we have already used that $$\varphi$$ does not appear -in the integrand to get a factor $$2 \pi$$. Next, let us take a closer look at the excitation energy in the denominator. Thanks to symmetry, we can always choose our coordinate system such that $$\vb{q}$$ points in the $$\theta = 0$$ direction, yielding: @@ -426,14 +442,20 @@ $$y \equiv \hbar (\omega + i \eta) / (4 \xi_F)$$ and $$c \equiv \cos{\theta}$$, giving: $$\begin{aligned} - \chi_0(\vb{q}, \omega) + \chi_0 &= \frac{k_F^3}{8 \pi^2 \xi_F} \int_0^1 \! \int_{-1}^1 \bigg( \frac{1}{-x^2 - x \kappa c + y} + \frac{1}{-x^2 - x \kappa c - y} \bigg) \kappa^2 \dd{c} \dd{\kappa} \end{aligned}$$ -Evaluating the integral over $$c$$ gives -a result that involves the complex natural logarithm $$\ln$$: +From now on, we need to treat $$\chi_0$$'s real and imaginary parts separately +using the [Sokhotski-Plemelj theorem](/know/concept/sokhotski-plemelj-theorem/). +The following is valid for the real part, +but is (for now) still written as a complex expression. +The point is that, to the best of my knowledge, +it is not practical to extract the imaginary part +from the "real part's complex result" so to speak. +So, hiding the [principal value](/know/concept/cauchy-principal-value/): $$\begin{aligned} \chi_0 @@ -494,13 +516,23 @@ $$\begin{aligned} \bigg) \end{aligned}$$ -We thus arrive at this expression +Finally, we also know that the [density of states](/know/concept/density-of-states/) +$$g$$ per unit volume of a Fermi gas is given by: + +$$\begin{aligned} + g(\xi_F) + = \frac{2}{4 \pi^2} \bigg( \frac{2 m}{\hbar^2} \bigg)^{3/2} \xi_F^{1/2} + = \frac{m k_F}{\pi^2 \hbar^2} +\end{aligned}$$ + +Now we officially take the real part, +and arrive at the following expression for the response function of non-interacting electrons: $$\begin{aligned} \boxed{ - \chi_0(\vb{q}, \omega) - = - \frac{m k_F}{\pi^2 \hbar^2} \: \mathcal{F}\bigg(\frac{|\vb{q}|}{2 k_F}, \: \frac{\hbar (\omega \!+\! i \eta)}{4 \xi_F}\bigg) + \Real{\chi_0(\vb{q}, \omega)} + = - g(\xi_F) \: \mathcal{F}\bigg(\frac{|\vb{q}|}{2 k_F}, \: \frac{\hbar \omega}{4 \xi_F}\bigg) } \end{aligned}$$ @@ -511,17 +543,144 @@ $$\begin{aligned} \boxed{ \mathcal{F}(x, y) \equiv \frac{1}{2} - + \frac{1}{8 x} \bigg( 1 - \Big(x \!+\! \frac{y}{x}\Big)^{\!2} \bigg) \ln\!\bigg( \frac{x + y/x + 1}{x + y/x - 1} \bigg) - + \frac{1}{8 x} \bigg( 1 - \Big(x \!-\! \frac{y}{x}\Big)^{\!2} \bigg) \ln\!\bigg( \frac{x - y/x + 1}{x - y/x - 1} \bigg) + + \frac{1}{8 x} \bigg( 1 - \Big(x + \frac{y}{x}\Big)^{\!2} \bigg) \ln\!\bigg| \frac{x + y/x + 1}{x + y/x - 1} \bigg| + + \frac{1}{8 x} \bigg( 1 - \Big(x - \frac{y}{x}\Big)^{\!2} \bigg) \ln\!\bigg| \frac{x - y/x + 1}{x - y/x - 1} \bigg| } \end{aligned}$$ -Keep in mind that these are complex logarithms, -whose branch cut should lie along the negative real axis, -such that the results' imaginary parts are always between $$-\pi$$ and $$\pi$$. -That way, it is consistent with alternative derivations -that use the [Sokhotski-Plemelj theorem](/know/concept/sokhotski-plemelj-theorem/) -(e.g. Mihaila's paper). +Now we move on to $$\chi_0$$'s imaginary part. +Recall the following expression from earlier: + +$$\begin{aligned} + \chi_0 + &= \frac{- k_F^3}{8 \pi^2 \xi_F} \frac{1}{x} \int_0^1 \! \int_{-1}^1 \bigg( + \frac{1}{x + y/x + \kappa c} + \frac{1}{x - y/x + \kappa c} + \bigg) \kappa^2 \dd{c} \dd{\kappa} +\end{aligned}$$ + +The Sokhotski-Plemelj theorem then states that the imaginary part is as shown below. +There is a nasty detail here regarding the positive infinitesimal $$\eta \to 0^{+}$$: +the first input term's denominator contains $$+ i \eta$$, +so the theorem can be applied normally, +but the second term has $$-i \eta$$, meaning the theorem's output must be negated! + +$$\begin{aligned} + \Imag{\chi_0} + &= \frac{-2 m k_F^3}{8 \pi^2 \hbar^2 k_F^2} \frac{1}{x} \int_0^1 \! \int_{-1}^1 \bigg( + \!-\! \pi \delta(z_{+} + \kappa c) + \pi \delta(z_{-} + \kappa c) + \bigg) \kappa^2 \dd{c} \dd{\kappa} + \\ + &= \frac{\pi m k_F}{4 \pi^2 \hbar^2} \frac{1}{x} \int_0^1 \bigg[ + \frac{1}{\kappa} \Theta(z_{+} + \kappa c) - \frac{1}{\kappa} \Theta(z_{-} + \kappa c) + \bigg]_{-1}^1 \kappa^2 \dd{\kappa} + \\ + &= \frac{\pi}{4 x} \: g(\xi_F) \int_0^1 \bigg( + \Theta(z_{+} + \kappa) - \Theta(z_{+} - \kappa) - \Theta(z_{-} + \kappa) + \Theta(z_{-} - \kappa) + \bigg) \kappa \dd{\kappa} +\end{aligned}$$ + +These integrals are easily evaluated +according to the following straightforward relations: + +$$\begin{aligned} + \int_0^1 \Theta(\alpha - \kappa) \: \kappa \dd{\kappa} + &= \frac{1}{2} \big( \alpha^2 - (\alpha^2 - 1) \: \Theta(\alpha - 1) \big) \: \Theta(\alpha) + \\ + \int_0^1 \Theta(\alpha + \kappa) \: \kappa \dd{\kappa} + &= \frac{1}{2} \big( \alpha^2 \: \Theta(\alpha) - \alpha^2 + 1 \big) \: \Theta(\alpha + 1) +\end{aligned}$$ + +Let us assume that $$y > 0$$ for now, +such that $$z_{+} > 0$$ and $$z_{+} > z_{-}$$. +We can then naively distinguish several options to be considered: + +1. $$z_{+} > z_{-} > 1 > 0 > -1$$. +2. $$z_{+} > 1 > z_{-} > 0 > -1$$. +3. $$z_{+} > 1 > 0 > z_{-} > -1$$. +4. $$z_{+} > 1 > 0 > -1 > z_{-}$$. +5. $$1 > z_{+} > z_{-} > 0 > -1$$. +6. $$1 > z_{+} > 0 > z_{-} > -1$$. +7. $$1 > z_{+} > 0 > -1 > z_{-}$$. + +It can be shown that #7 is impossible +due to the definitions of $$z_{+}$$ and $$z_{-}$$. +A tedious investigation of the six remaining cases then yields: + +1. In cases #1 or #4, + or, equivalently, if both $$|z_{+}| > 1$$ and $$|z_{-}| > 1$$, + the result vanishes: + + $$\begin{aligned} + \Imag{\chi_0} + = 0 + \end{aligned}$$ + + An alternative statement of those conditions can be found, namely: + + $$\begin{aligned} + \begin{cases} + y > x^2 + x + &\mathrm{if} \: x < 1 + \\ + x^2 - x > y > 0 + &\mathrm{if} \: x > 1 + \end{cases} + \end{aligned}$$ + +2. In cases #2 or #3, + or, equivalently, if both $$|z_{+}| > 1$$ and $$|z_{-}| < 1$$, + the result is parabolic in $$y$$. + These conditions can be restated as $$x^2 + x > y > |x^2 - x|$$. + + $$\begin{aligned} + \Imag{\chi_0} + &= -\frac{\pi}{8 x} \: g(\xi_F) \: (1 - z_{-}^2) + \end{aligned}$$ + +3. In cases #5 or #6, + or, equivalently, if both $$|z_{+}| < 1$$ and $$|z_{-}| < 1$$ + the result is linear in $$y$$. + These conditions can be restated as $$-(x^2 - x) > y > 0$$. + + $$\begin{aligned} + \Imag{\chi_0} + &= \frac{\pi}{8 x} \: g(\xi_F) \: (z_{-}^2 - z_{+}^2) + = - \frac{\pi}{2 x} \: g(\xi_F) \: y + \end{aligned}$$ + +Repeating the analysis for $$y < 0$$ and putting everything together, +we arrive at the following formula for the imaginary part +of the non-interacting response function: + +$$\begin{gathered} + \boxed{ + \Imag{\chi_0(\vb{q}, \omega)} + = - g(\xi_F) \: \mathcal{G}\bigg( \frac{|\vb{q}|}{2 k_F}, \: \frac{\hbar \omega}{4 \xi_F} \bigg) + } + \\ + \boxed{ + \mathcal{G}(x, y) + \equiv + \begin{cases} + 0 + &\mathrm{if} \: |y| > x^2 + x > 0 + \\ + \sgn(y) \displaystyle\frac{\pi}{8 x} \bigg( 1 - \Big( x - \displaystyle\frac{|y|}{x} \Big)^2 \bigg) + &\mathrm{if} \: x^2 + x > |y| > |x^2 - x| + \\ + \displaystyle\frac{\pi}{2 x} y + &\mathrm{if} \: \!-\!(x^2 - x) > |y| > 0 + \\ + 0 + &\mathrm{if} \: x^2 - x > |y| > 0 + \end{cases} + } +\end{gathered}$$ + +We are being a bit sloppy here by ignoring the boundaries, +e.g. $$|y| = x^2 - x$$. +Fortunately, they are all naturally continuous, +so either of the two neighboring formulas can be used. @@ -594,7 +753,7 @@ $$\begin{aligned} \boxed{ \mathcal{F}(x, 0) = \frac{1}{2} - + \frac{1}{4 x} (1 - x^2) \ln\!\bigg( \frac{x + 1}{x - 1} \bigg) + + \frac{1}{4 x} (1 - x^2) \ln\!\bigg| \frac{x + 1}{x - 1} \bigg| } \end{aligned}$$ diff --git a/source/know/concept/parsevals-theorem/index.md b/source/know/concept/parsevals-theorem/index.md index b2db490..06e9406 100644 --- a/source/know/concept/parsevals-theorem/index.md +++ b/source/know/concept/parsevals-theorem/index.md @@ -45,7 +45,8 @@ $$\begin{aligned} &= 2 \pi B^2 \iint \tilde{f}^*(k') \: \tilde{g}(k) \: \delta\big(s (k' \!-\! k)\big) \dd{k'} \dd{k} \\ &= \frac{2 \pi B^2}{|s|} \int_{-\infty}^\infty \tilde{f}^*(k) \: \tilde{g}(k) \dd{k} - = \frac{2 \pi B^2}{|s|} \inprod{\tilde{f}}{\tilde{g}} + \\ + &= \frac{2 \pi B^2}{|s|} \inprod{\tilde{f}}{\tilde{g}} \end{aligned}$$ Where $$\delta(k)$$ is the [Dirac delta function](/know/concept/dirac-delta-function/). @@ -67,7 +68,8 @@ $$\begin{aligned} &= 2 \pi A^2 \iint f^*(x') \: g(x) \: \delta\big(s (x \!-\! x')\big) \dd{x'} \dd{x} \\ &= \frac{2 \pi A^2}{|s|} \int_{-\infty}^\infty f^*(x) \: g(x) \dd{x} - = \frac{2 \pi A^2}{|s|} \inprod{f}{g} + \\ + &= \frac{2 \pi A^2}{|s|} \inprod{f}{g} \end{aligned}$$ {% include proof/end.html id="proof-fourier" %} diff --git a/source/know/concept/schwartz-distribution/index.md b/source/know/concept/schwartz-distribution/index.md index 2492d91..3d5186f 100644 --- a/source/know/concept/schwartz-distribution/index.md +++ b/source/know/concept/schwartz-distribution/index.md @@ -11,7 +11,7 @@ A **Schwartz distribution**, also known as a **generalized function**, is a generalization of a function, allowing us to work with otherwise pathological definitions. -Notable examples of distributions are +Notable examples of such distributions are the [Dirac delta function](/know/concept/dirac-delta-function/) and the [Heaviside step function](/know/concept/heaviside-step-function/), whose unusual properties are justified by this generalization. @@ -31,13 +31,13 @@ Furthermore, all test functions must be infinitely differentiable. These are quite strict requirements. The **space of distributions** $$\mathcal{S}'$$ (note the prime) -is then said to consist of *functionals* $$f[\phi]$$ -which map a test function $$\phi$$ from $$\mathcal{S}$$, +is then said to consist of *functionals* $$\delta[\phi]$$ +that map a test function $$\phi$$ from $$\mathcal{S}$$ to a number from $$\mathbb{C}$$; -this is often written as $$\Inprod{f}{\phi}$$. +this is often written as $$\Inprod{\delta}{\phi}$$. This notation looks like the inner product of a [Hilbert space](/know/concept/hilbert-space/), -for good reason: any well-behaved function $$f(x)$$ can be embedded +and there is a good reason for that: any well-behaved function $$f(x)$$ can be embedded into $$\mathcal{S}'$$ by defining the corresponding functional $$f[\phi]$$ as follows: $$\begin{aligned} @@ -49,10 +49,11 @@ $$\begin{aligned} Not all functionals qualify for $$\mathcal{S}'$$: they also need to be linear in $$\phi$$, and **continuous**, which in this context means: if a series $$\phi_n$$ -converges to $$\phi$$, then $$\Inprod{f}{\phi_n}$$ -converges to $$\Inprod{f}{\phi}$$ for all $$f$$. +converges to $$\phi$$, then $$\Inprod{\delta}{\phi_n}$$ +converges to $$\Inprod{\delta}{\phi}$$ for all $$\delta$$. -The power of this generalization is that $$f(x)$$ does not need to be well-behaved: +The power of the generalization is that $$f(x)$$ +in fact does not *need* to be well-behaved: for example, the Dirac delta function can also be used, whose definition is nonsensical *outside* of an integral, but perfectly reasonable *inside* one. @@ -60,7 +61,7 @@ By treating it as a distribution, we gain the ability to sanely define e.g. its derivatives. Using the example of embedding a well-behaved function $$f(x)$$ into $$\mathcal{S}$$, -we can work out what the derivative of a distribution is: +we can work out what the derivative of a distribution is using partial integration: $$\begin{aligned} \Inprod{f'}{\phi} @@ -68,20 +69,21 @@ $$\begin{aligned} = \Big[ f(x) \: \phi(x) \Big]_{-\infty}^\infty - \int_{-\infty}^\infty f(x) \: \phi'(x) \dd{x} \end{aligned}$$ -The test function removes the boundary term, yielding the result -$$- \Inprod{f}{\phi'}$$. Although this was an example for a specific $$f(x)$$, -we use it to define the derivative of any distribution: +The test function removes the first term, +yielding the result $$- \Inprod{f}{\phi'}$$. +Although this was an example for a well-behaved $$f(x)$$, +we use it to define the derivative of any distribution $$\delta \in \mathcal{S}'$$: $$\begin{aligned} \boxed{ - \Inprod{f'}{\phi} = - \Inprod{f}{\phi'} + \Inprod{\delta'}{\phi} + \equiv - \Inprod{\delta}{\phi'} } \end{aligned}$$ Using the same trick, we can find the -[Fourier transform](/know/concept/fourier-transform/) (FT) -of a generalized function. -We define the FT as follows, +[Fourier transform](/know/concept/fourier-transform/) (FT) of a distribution. +Let us define the FT like so, but be prepared for some switching of the names $$k$$ and $$x$$: $$\begin{aligned} @@ -89,30 +91,34 @@ $$\begin{aligned} = \int_{-\infty}^\infty \phi(k) \exp(- i k x) \dd{k} \end{aligned}$$ -The FT of a Schwartz distribution $$f$$ then turns out to be as follows: +The FT of a well-behaved $$f(x)$$ is then as follows +(this is basically [Parseval's theorem](/know/concept/parsevals-theorem/)): $$\begin{aligned} \inprod{\tilde{f}}{\phi} &= \int_{-\infty}^\infty \tilde{f}(k) \: \phi(k) \dd{k} - = \iint_{-\infty}^\infty f(x) \exp(- i k x) \: \phi(k) \dd{x} \dd{k} + \\ + &= \iint_{-\infty}^\infty f(x) \exp(- i k x) \: \phi(k) \dd{x} \dd{k} \\ &= \int_{-\infty}^\infty f(x) \: \tilde{\phi}(x) \dd{x} - = \inprod{f}{\tilde{\phi}} + \\ + &= \inprod{f}{\tilde{\phi}} \end{aligned}$$ -Note that the ordinary FT $$\tilde{f}(k) = \hat{\mathcal{F}}\{f(x)\}$$ is -already a 1:1 mapping of test functions $$\phi \leftrightarrow \tilde{\phi}$$. -As it turns out, -in this generalization it is also a 1:1 mapping of distributions in $$\mathcal{S}'$$, -defined as: +So we defined the FT and derived one of its properties, +but to generalize to Schwartz distributions $$\delta$$, we swap the roles: +the property is an axiom, and serves as the definition of the FT $$\tilde{\delta}$$: $$\begin{aligned} \boxed{ - \inprod{\tilde{f}}{\phi} - = \inprod{f}{\tilde{\phi}} + \inprod{\tilde{\delta}}{\phi} + \equiv \inprod{\delta}{\tilde{\phi}} } \end{aligned}$$ +It can be shown that this generalization is a 1:1 mapping +between distributions in $$\mathcal{S}'$$. + ## References diff --git a/source/know/concept/time-dependent-perturbation-theory/index.md b/source/know/concept/time-dependent-perturbation-theory/index.md index 841c219..b0ffa42 100644 --- a/source/know/concept/time-dependent-perturbation-theory/index.md +++ b/source/know/concept/time-dependent-perturbation-theory/index.md @@ -78,89 +78,6 @@ and we cannot go any further without considering a specific $$\hat{H}_1$$. -## Sinusoidal perturbation - -Arguably the most important perturbation -is a sinusoidally-varying potential, which represents -e.g. incoming electromagnetic waves, -or an AC voltage being applied to the system. -In this case, $$\hat{H}_1$$ has the following form: - -$$\begin{aligned} - \hat{H}_1(\vec{r}, t) - \equiv V(\vec{r}) \sin(\omega t) - = \frac{1}{2 i} V(\vec{r}) \: \big( \exp(i \omega t) - \exp(-i \omega t) \big) -\end{aligned}$$ - -We abbreviate $$V_{mn} = \matrixel{m}{V}{n}$$, -and take the first-order correction formula: - -$$\begin{aligned} - c_m^{(1)}(t) - &= - \frac{1}{2 \hbar} \sum_{n} V_{mn} c_n^{(0)} - \int_0^t \exp\!\big(i \tau (\omega_{mn} \!+\! \omega)\big) - \exp\!\big(i \tau (\omega_{mn} \!-\! \omega)\big) \dd{\tau} - \\ - &= \frac{i}{2 \hbar} \sum_{n} V_{mn} c_n^{(0)} - \bigg( \frac{\exp\!\big(i t (\omega_{mn} \!+\! \omega) \big) - 1}{\omega_{mn} + \omega} - + \frac{\exp\!\big(i t (\omega_{mn} \!-\! \omega) \big) - 1}{\omega_{mn} - \omega} \bigg) -\end{aligned}$$ - -For simplicity, we let the system start in a known state $$\Ket{a}$$, -such that $$c_n^{(0)} = \delta_{na}$$, -and we assume that the driving frequency is close to resonance $$\omega \approx \omega_{ma}$$, -such that the second term dominates the first, which can then be neglected. -We thus get: - -$$\begin{aligned} - c_m^{(1)}(t) - &= i \frac{V_{ma}}{2 \hbar} \frac{\exp\!\big(i t (\omega_{ma} \!-\! \omega) \big) - 1}{\omega_{ma} - \omega} - \\ - &= i \frac{V_{ma}}{2 \hbar} - \frac{\exp\!\big(i t (\omega_{ma} \!-\! \omega) / 2 \big) - \exp\!\big(\!-\! i t (\omega_{ma} \!-\! \omega) / 2 \big)}{\omega_{ma} - \omega} - \: \exp\!\big(i t (\omega_{ma} \!-\! \omega) / 2 \big) - \\ - &= - \frac{V_{ma}}{\hbar} - \frac{\sin\!\big( t (\omega_{ma} \!-\! \omega) / 2 \big)}{\omega_{ma} - \omega} - \: \exp\!\big(i t (\omega_{ma} \!-\! \omega) / 2 \big) -\end{aligned}$$ - -Taking the norm squared yields the **transition probability**: -the probability that a particle that started in state $$\Ket{a}$$ -will be found in $$\Ket{m}$$ at time $$t$$: - -$$\begin{aligned} - \boxed{ - P_{a \to m} - = |c_m^{(1)}(t)|^2 - = \frac{|V_{ma}|^2}{\hbar^2} \frac{\sin^2\!\big( (\omega_{ma} - \omega) t / 2 \big)}{(\omega_{ma} - \omega)^2} - } -\end{aligned}$$ - -The result would be the same if $$\hat{H}_1 \equiv V \cos(\omega t)$$. -However, if instead $$\hat{H}_1 \equiv V \exp(- i \omega t)$$, -the result is larger by a factor of $$4$$, -which can cause confusion when comparing literature. - -In any case, the probability oscillates as a function of $$t$$ -with period $$T = 2 \pi / (\omega_{ma} \!-\! \omega)$$, -so after one period the particle is back in $$\Ket{a}$$, -and after $$T/2$$ the particle is in $$\Ket{b}$$. -See [Rabi oscillation](/know/concept/rabi-oscillation/) -for a more accurate treatment of this "flopping" behaviour. - -However, when regarded as a function of $$\omega$$, -the probability takes the form of -a sinc-function centred around $$(\omega_{ma} \!-\! \omega)$$, -so it is highest for transitions with energy $$\hbar \omega = E_m \!-\! E_a$$. - -Also note that the sinc-distribution becomes narrower over time, -which roughly means that it takes some time -for the system to "notice" that -it is being driven periodically. -In other words, there is some "inertia" to it. - - - ## References 1. D.J. Griffiths, D.F. Schroeter, *Introduction to quantum mechanics*, 3rd edition, |
