summaryrefslogtreecommitdiff
path: root/latex/know/concept/slater-determinant
diff options
context:
space:
mode:
Diffstat (limited to 'latex/know/concept/slater-determinant')
-rw-r--r--latex/know/concept/slater-determinant/source.md43
1 files changed, 43 insertions, 0 deletions
diff --git a/latex/know/concept/slater-determinant/source.md b/latex/know/concept/slater-determinant/source.md
new file mode 100644
index 0000000..5d13c56
--- /dev/null
+++ b/latex/know/concept/slater-determinant/source.md
@@ -0,0 +1,43 @@
+% Slater determinant
+
+
+# Slater determinant
+
+In quantum mechanics, the **Slater determinant** is a trick to create an
+antisymmetric wave function for a system of $N$ fermions.
+
+Given an orthogonal set of individual states $\psi_n(x)$, we write
+$\psi_n(x_n)$ to say that particle $x_n$ is in state $\psi_n$. Now the
+goal is to find an expression for an overall many-particle wave
+function $\Psi(x_1, ..., x_N)$ that satisfies the
+[Pauli exclusion principle](/know/concept/pauli-exclusion-principle/).
+Enter the Slater determinant:
+
+$$\begin{aligned}
+ \boxed{
+ \Psi(x_1, ..., x_N)
+ = \frac{1}{\sqrt{N!}} \det\!
+ \begin{bmatrix}
+ \psi_1(x_1) & \cdots & \psi_N(x_1) \\
+ \vdots & \ddots & \vdots \\
+ \psi_1(x_N) & \cdots & \psi_N(x_N)
+ \end{bmatrix}
+ }\end{aligned}$$
+
+Swapping the state of two particles corresponds to exchanging two rows
+in the matrix, which flips the sign of the determinant. Similarly,
+exchanging two columns means swapping two states, which also results in
+a sign change. Finally, putting two particles into the same state makes
+$\Psi$ vanish.
+
+Note that not all valid many-particle fermionic wave functions can be
+written as a single Slater determinant; a linear combination of multiple
+may be needed. Nevertheless, an appropriate choice of the input set
+$\psi_n(x)$ can optimize how well a single determinant approximates a
+given $\Psi$.
+
+In fact, there exists a similar trick for bosons, where the goal is to
+create a symmetric wave function which allows multiple particles to
+occupy the same state. In this case, one needs to take the **Slater
+permanent** of the same matrix, which is simply the determinant, but with
+all minuses replaced by pluses.